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While pipeline transportation is the most common method for moving CO2 from capture facilities to storage sites, ship transportation offers important advantages in certain scenarios: long distances across oceans, access to offshore storage sites far from shore, flexible routing that can serve multiple sources and sinks, and potential for stepwise CCS deployment without requiring large upfront pipeline infrastructure investments. ISO/TR 27929:2025 addresses this transportation mode by providing comprehensive guidelines for ship-based CO2 transportation in the CCS chain.
Developed by ISO/TC 265, this Technical Report covers the full ship transportation chain including cargo containment systems, loading and unloading operations, ship design considerations, boil-off gas management, maritime safety, and integration with port facilities. It builds on experience from the established LPG and LNG shipping industries while addressing the unique properties of CO2, particularly its higher density, different phase behavior, and the potential for dry ice formation during pressure and temperature changes.
CO2 can be transported by ship in three states: low-temperature liquid (approximately -50°C at 0.7 MPa), medium-temperature liquid (-30 to -10°C at 1.5-3.0 MPa), or ambient-temperature dense-phase (near-ambient temperature at 4.0-7.0 MPa). Each state has distinct advantages and disadvantages. Low-temperature liquid minimizes pressure requirements but requires significant energy for refrigeration. Ambient-temperature dense-phase eliminates the need for onboard refrigeration but requires heavier pressure vessels. The standard provides guidance on selecting the optimal cargo state based on voyage distance, port facilities, upstream capture conditions, and downstream storage requirements.
| Cargo State | Temperature | Pressure | Density | Key Advantage | Key Challenge |
|---|---|---|---|---|---|
| Low-temperature liquid | -50°C | 0.7 MPa | ~1,150 kg/m³ | Low-pressure tanks | Refrigeration energy |
| Medium-temperature liquid | -20°C | 2.0 MPa | ~950 kg/m³ | Balance of pressure and temperature | Complex tank design |
| Dense-phase (ambient) | 10-20°C | 5.0 MPa | ~800 kg/m³ | No refrigeration needed | Heavy pressure vessels |
The standard reviews tank types suitable for CO2 service, adapted from the IMO International Gas Carrier (IGC) Code classification. Type C pressure vessels (cylindrical or spherical, designed for full containment pressure) are the most common choice for CO2 carriers due to their ability to handle the full range of potential operating pressures. Type C tanks for CO2 service require materials with adequate low-temperature toughness if operating in the liquid state range, or adequate strength at elevated pressure for dense-phase operation. The standard addresses material selection considerations including the need for impact testing at the minimum design temperature and resistance to CO2 corrosion in the presence of water.
ISO/TR 27929 provides detailed guidance on cargo transfer procedures for both loading (capture facility to ship) and unloading (ship to storage facility or pipeline). Key considerations include: pre-cooling of cargo tanks and transfer lines, pressure management during transfer to prevent two-phase flow or dry ice formation, vapor return systems to balance pressure between the ship and shore, and emergency shutdown (ESD) systems. The standard emphasizes the importance of compatibility between ship and shore transfer systems, recommending standardized coupler sizes and communication protocols.
CO2 carriers, particularly those operating at low temperature, experience heat ingress that causes a portion of the cargo to vaporize (boil-off gas or BOG). Unlike LNG carriers where BOG is typically used as fuel, CO2 BOG cannot be vented to the atmosphere (it is a greenhouse gas) and is not suitable as ship fuel. The standard addresses BOG management strategies including: reliquefaction (recondensing the BOG and returning it to the cargo tanks), pressure build-up management (allowing the tank pressure to rise within design limits), and cold utilization (using the refrigeration capacity of the BOG for other shipboard systems). The standard provides guidance on selecting the appropriate BOG management strategy based on voyage duration, tank design, and environmental regulations.
ISO/TR 27929 addresses maritime safety comprehensively, recognizing that CO2 presents unique hazards compared to other gas cargoes. CO2 is classified as a toxic and asphyxiant gas — high concentrations can cause rapid incapacitation and death. The standard provides guidance on cargo-area ventilation, gas detection systems, personal protective equipment (self-contained breathing apparatus), and emergency response procedures specific to CO2. Regulatory compliance with the IMO IGC Code and International Convention for the Prevention of Pollution from Ships (MARPOL) is addressed, noting that CO2 carriers must meet the same stringent safety standards as other gas carriers. The standard also addresses the evolving regulatory landscape, including potential future requirements under the IMO’s greenhouse gas reduction framework.
The standard addresses the shore-side infrastructure required for CO2 shipping operations. Port facilities must include: liquefaction plants or temporary storage (if CO2 is received as a gas from pipelines), intermediate storage tanks, loading arms and hoses rated for CO2 service, vapor return lines, and emergency response equipment. The standard provides guidance on the sizing of intermediate storage to ensure that ship loading operations are not disrupted by variations in CO2 supply from capture facilities. For ports that may serve multiple CCS projects, the standard recommends standardized interfaces to maximize operational flexibility.