Measurement of Carbon Dioxide, Carbon Monoxide, and Oxides of Nitrogen in Diesel Exhaust

This article covers the SAE J177 recommended practice for analyzing carbon dioxide, carbon monoxide, and oxides of nitrogen in diesel engine exhaust under steady-state conditions. The standard relies on nondispersive infrared (NDIR) techniques for CO2, CO, and NO, and chemiluminescence for total NOx. Proper execution of this method ensures accurate, repeatable emissions data for development, certification, and research.

Scope and Measurement Methods

SAE J177 applies to diesel engines or vehicles using diesel engines operating at a constant speed and load with stabilized temperatures and pressures—collectively termed steady-state. Continuous sampling is used, and the exhaust gas is directed through a system of filters, driers, condensers, and analyzers. NDIR is specified for carbon dioxide, carbon monoxide, and nitric oxide; total oxides of nitrogen (NOx) can be measured by chemiluminescence or NDIR methods described in the standard.

🛠️ Range Selection: Selecting the correct analyzer range is critical. Typical ranges from J177 are shown below, and dual- or stacked-cell designs allow flexibility while maintaining ±1% full-scale accuracy.
Component Typical Ranges
CO2 0–5% and 0–16%
CO 0–500 ppm, 0–1000 ppm, 0–2500 ppm
NO 0–500 ppm, 0–1000 ppm, 0–1500 ppm

System Configuration and Calibration Best Practices

The sampling train includes a probe, particulate filter, cooler/condenser, chemical drier, flow controls, and the analyzer(s). A bypass line around the drier and filter is provided to avoid component damage when analyzing wet samples. J177 emphasizes the use of NIST-traceable calibration gases with a concentration known to ±2% and routine span checks to verify instrument response.

Engineers must maintain steady-state conditions before and during measurement. Variations in speed or load alter the exhaust composition and invalidate results. Humidity of the intake air also affects NOx formation; correction factors based on published CRC reports are applied to account for this interference.

⚠️ Humidity Correction: Failure to correct for intake-air humidity can introduce significant errors, especially for NOx measurements. Always record humidity and apply the recommended correction from J177 or supporting reports.

Common Questions and Troubleshooting

🔍 What are the primary methods required by J177?
NDIR is used for CO2, CO, and NO; chemiluminescence is recommended for total NOx. Both methods require careful calibration and sample conditioning.

🔍 How do I set up an NDIR analyzer for diesel exhaust?
Follow the system diagram in J177. Ensure the sample line is heated to prevent condensation, install appropriate filters, and calibrate with NIST-traceable gases. Use the recommended ranges for the expected concentration levels.

🔍 Why is humidity correction necessary?
Water vapor in the exhaust interferes with the NDIR measurement and also influences the formation of NOx in the engine. Correcting for humidity ensures reported values reflect true engine-out emissions.

🔍 What are the key steady-state requirements?
The engine must operate at a constant speed and load until temperatures stabilize. This usually takes several minutes, and no measurement should be taken until the system confirms stable conditions.

Adhering to SAE J177 provides a consistent framework for diesel exhaust emissions measurement. By applying the correct methods, calibration practices, and environmental corrections, engineers can obtain reliable data for development and compliance purposes.

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