D3193-24 – Standard Test Method Technical Guide

ASTM D3193-24 provides the standard specification for ethylbenzene, a critical industrial chemical primarily used as an intermediate in the production of styrene monomer. Under the jurisdiction of Committee D16, this standard received its latest revision in 2024.

⚗️ Scope and Referenced Documents

This specification covers the compositional and quality requirements for ethylbenzene. For determining conformance, observed or calculated values must be rounded “to the nearest unit” in the last right-hand digit of the specification limit, according to Practice E29. Values stated in SI units are regarded as the standard. The standard strongly emphasizes safety, explicitly requiring users to consult current OSHA regulations (29 CFR 1910.1000 and 1910.1200), the supplier’s Safety Data Sheet (SDS), and all applicable local regulations. Key referenced ASTM standards guide the required analytical testing and proper handling of the material.

Always consult the latest edition of the standard and the safety data sheet. The user assumes responsibility for establishing safe handling practices.

📊 Property Requirements and Test Methods

The core technical requirements of D3193-24 establish strict limits on purity and key aromatic impurities. The table below summarizes these specifications and the ASTM methods required for their verification.

🟦 Property📏 Specification🎯 ASTM Test Method
Purity, min, weight %99.00D5060 or D7504
Benzene, max, weight %0.1D5060 or D7504
Toluene, max, weight %0.4D5060 or D7504
Xylenes, max, weight %0.4D5060 or D7504

🧪 Analytical Procedures and Quality Assurance

Conformance to the ethylbenzene specification relies on a battery of well-defined analytical methods. These range from gas chromatography for impurities to specialized techniques for trace elements and physical properties.

⚡ Test Method🔍 Analytical Purpose
D5060 / D7504Determination of impurities by Gas Chromatography
D5386 / D8005Color of liquids (Tristimulus / Platinum-Cobalt Scale)
D5194 / D5808 / D7536Trace chloride analysis in aromatics
D7183Total sulfur determination by UV fluorescence
D7359Total F, Cl, S by Combustion Ion Chromatography (CIC)
E2680Visual inspection procedure (appearance)
D3437Standard practice for sampling and handling
Ensure all measurement values used to determine conformance are properly rounded to the nearest unit in the last right-hand digit as defined by the specification limit (Practice E29).

❓ Frequently Asked Questions

🔍 What is the minimum purity standard for ethylbenzene per D3193-24? The specification mandates a minimum purity of 99.00 weight percent.
💡 What test methods are specified for verifying purity and impurity levels? Purity, benzene, toluene, and xylene content are determined using ASTM D5060 or D7504, both of which employ Gas Chromatography.
How should specification results be evaluated for conformance? The standard stipulates that all observed or calculated values must be rounded “to the nearest unit” in the last right-hand digit used in the specification limit, as per Practice E29.
📌 What safety regulations are cited in the standard? Users must comply with current OSHA regulations (29 CFR 1910.1000 and 1910.1200) and review the supplier’s Safety Data Sheet and local regulations.

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